The Identity of the Substance This category features required information on the identity of the material as given on the product label. Fortunately, the Hazard Communication Standard created by OSHA requires that employers who use hazardous substances must make MSDSs available for employee use and reference, and must provide appropriate warning labels on containers of hazardous substances within the facility. As a concerned citizen, you need to be aware of where hazards may exist and know how to recognize and report a possible problem. In both cases, this is far less than the lifecycle emission rates for natural . Mitigation: This phase focuses on reducing or eliminating the risks and impacts of disasters through long-term and short-term measures. Define cardiac cycle, systole, and diastole. State laws often close loopholes in Federal legislation (such as transportation of hazardous materials within State lines) to provide further citizen protection. << /Length 7 0 R /Filter /LZWDecode >> A score assigned to the site by the State and reviewed by EPA usually determines the NPL ranking. Off-Site Disposal. FIRE AND EXPLOSION DATALOWERUPPERFlash Point and MethodAutoignition Temp.Flammability Limits In AirN/AN/AN/AN/AN/AExtinguishing Media: Water or carbon dioxide. Ingestion can cause throat burns and severe swelling of windpipe. b) Graph FFF versus xxx from x=0x=0x=0 to x=lx=lx=l. If there are numerous areas where the responders could enter the facility, there should be numerous placards. Dupont de Nemours Co., Inc.SECTION II. For example, the cost of painting a surface with a lead based paint should include the cost of removing the paint during repair or maintenance operations, as well as the cost of applying the paint. %PDF-1.1 The UN ID numbers are ______ digits long. A) three. * *Get medical attention promptly for all affected persons. During storage? The five phases of a hazardous material's life does not include production transportation storage elimination and disposal.? Your LEPC should be able to give you precise information about where reportable quantities of extremely hazardous materials are stored or released from fixed sites in your community. Small volunteer fire departments often lack the personnel and skills required to inspect and maintain records on hazardous materials stored locally; some train citizen volunteers to assist them in these tasks. Phosphate fertilizer can also cause problems. endobj How do you telepathically connet with the astral plain? Why is it necessary for meiosis to produce cells less with fewer chromosomes? Many materials do not have such warning signals as smell or taste. An LCA is a systematic analysis of environmental impact over the course of the entire life cycle of a product, material, process, or other measurable activity. By examining how materials are used throughout their life cycle, an SMM approach seeks to: How our society uses materials is fundamental to our economic and environmental future. First responders use several resources to identify hazardous materials and respond appropriately: The Emergency Response Guidebook. an estimated 42 percent of total U.S. greenhouse gas emissions, Sustainable Materials Management: The Road Ahead, Guidance on Life-Cycle Thinking and Its Role in Environmental Decision Making. Protective clothing is also important whenever pesticides are applied. Additional explosive devices are placed specifically to target individuals and personnel/responders because terrorists seek to: disrupt response efforts and generate chaos and fear in the civilian population. Does Dr. Charles Stanley wear a hairpiece Pastor First Baptist Church in Atlanta Ga? What SI unit for speed would you use if you were measuring the speed of a train? c. modification of vehicles to support heavier loads. For example, a product may be re-designed so it is manufactured using different, fewer, less toxic and more durable materials. Further, the manufacturer has a similar relationship with its suppliers, which helps the manufacturer respond more quickly to changing demands, including reducing environmental impacts along the supply chain. When approaching an incident scene, awareness-level responders should remember to apply what concept? Assure we have sufficient resources to meet todays needs and those of the future. endobj Which acronym is used to identify the four components of an IED? A sensitive issue in this type of treatment is how to dispose of the contaminated carbon. Undocumented waste sites or underground storage tanks may exist, or large quantities of toxic materials may be regularly transported through your community. A .gov website belongs to an official government organization in the United States. If no relevant information can be located for a required category, the MSDS will be marked to indicate that no applicable information has been found for that entry. (Radon, the second leading cause of lung cancer in the United States, is a colorless, odorless, tasteless gas.) The five phases of the Hazardous Materials (HazMat) life cycle are production, transportation, storage, use, and: The five phases of the hazardous materials life cycle are production, transportation, storage, use, and DISPOSAL. This lets you know exactly how current an MSDS is. Had it been, this information might have been found in Sections II or VII. A lock (LockA locked padlock) or https:// means youve safely connected to the .gov website. MSDS forms are found in a wide variety of formats, but regardless of the format, they must contain certain key information for employee reference. The identification system specified in NFPA 704 is intended to enable first responders to easily decide whether to evacuate the area or to commence emergency control procedures and to also provide information to assist in selecting firefighting tactics and emergency procedures. Under this approach, hazardous materials are removed to a RCRA site. As mentioned at the start of this discussion there are many additional considerations regarding hazardous materials. TLVs are airborne concentrations of hazardous substances and their values vary from one substance to another. For every one percent increase in gross domestic product, raw material use has risen by 0.4 percent. tension-building phase. This information can be found in Section IX of the sample MSDS form at the end of this unit. c) Graph the torque versus xxx from x=0x=0x=0 to x=lx=lx=l. The safety life-cycle for the process industry sector comes from the IEC 61511 standard. (2) acute battering phase. Some MSDS forms may be updated once or twice a year, while others, such as those for steel, do not require frequent updating. Preclude from exposure workers with kidney disease, osteofluorosis, or impaired pulmonary function. READING AND INTERPRETING A MATERIAL SAFETY DATA SHEET (MSDS) Hazardous materials are common in the modern workplace, and it is clearly important that workers know when they are handling these materials to ensure adequate protection and compliance with the proper safety procedures. A) UN/NA identification number, the name of the material, and a placard. Sustainable materials management (SMM) is a systematic approach to using and reusing materials more productively over their entire life cycles. References 8. The identification number on the placard is 1978. The primary objective of the Hazardous Materials Response Team is to provide guidance and technical expertise, in the mitigation and removal of hazardous . > o q j k l m n | ` bjbj @ D k k k k \ k 4 z *m *m ( Rm Rm zm rr 6 r r - / / / / / / $ ( h J S }x q | Pr " }x }x S Rm zm Z h +} +} +} }x p Rm ( r 8 zm - +} }x - +} +} M 6 zm m `HC7W k x 1 6 Q ~ 0 g R y " l r , s +} t vu r r r S S | p r r r }x }x }x }x D7 J= - J= Unit 3: IDENTIFYING HAZARDOUS MATERIALS OBJECTIVES: In this unit, you will learn about: Clues that indicate the presence of hazardous materials How to identify where hazardous materials are located in your community Common problems and remedies for hazardous materials sites How to use a Material Safety Data Sheet (MSDS) to learn more about acutely toxic substances How do you know where hazardous materials exist in your community, and whether or not they pose a threat to public health? Question Asked 9 hours 46 minutes ago|4/17/2023 3:30:20 PM MATERIAL IDENTIFICATIONMATERIAL NAME: HYDROFLUoric acid, aqueous (47-70%) DESCRIPTION: A solution hydrogen fluoride gas in water. Sometimes no sign reveals that hazardous chemicals exist beneath the surface of the ground, but occasionally unusual circumstances suggest their presence. On the National Fire Protection Association (NFPA) 704 fixed facility markings, the instability/reactivity hazard rating appears on the right side of the diamond and is what color? endobj Physical hazard materials are those classified as an explosive, flammable cryogen, flammable gas, flammable solid, ignitible liquid, organic peroxide, oxidizer, oxidizing cryogen, pyrophoric, unstable (reactive), or water-reactive material. Use protection suitable for conditions. Continue washing 2-4 hours with water; or preferably if available, soak in iced zephiran (0.13%), Epsom salt, or 70% denatured ethyl alcohol solution for 1-4 hours, depending on severity of burns. Which Department of Transportation (DOT) hazard class contains organic peroxides and oxidizers? Citizens near a site using this method need to ask questions about the rate at which toxic elements are released into the atmosphere, particularly if residential areas are located near the stripping tower. APPROVALS: MIS CRDIndustrial Hygiene and Safety MEDICAL REVIEW: 14 May 1981 GENIUM PUBLISHING CHECK YOUR MEMORY (Answers are on page C-4) The __________ usually prepares the MSDS of a hazardous substance: The manufacturer or distributor The supplier or the shipper The end user or the buyer The shipper or the receiver To inform workers of hazards a chemical may pose, OSHA requires employers to develop a: Hazardous Materials Program Hazardous Waste Program Hazard Communication Program Worker Right to Know Program Health hazards of a given chemical would be found in what section of the MSDS? cycle of violence. Consider the five phases of the life cycle of a hazardous material-production, transportation, storage, use, and disposal. Reduce toxic chemicals and environmental impacts throughout the material life cycle. It . SPILL, LEAK, AND DISPOSAL PROCEDURESNotify safety personnel, provide adequate ventilation, and remove ignition sources since hydrogen may be generated by reactions with metals. Thoughtful policies are needed at each phase to protect local residents from unnecessary health risks. Firefighters should wear self-contained breathing-apparatus, eye protection, and complete body protection equipment when fighting an HF fire.SECTION V. REACTIVITY DATAHydrofluoric acid is a stable chemical when used and stored under proper conditions. In detecting clues to the presence of Hazardous Materials (HazMat) at the scene of an incident, using the sense of touch, taste, or __________ is not recommended. Due to their importance to our national security and economy, some industries are more susceptible to terrorist threats. Based on the map shown below, where in this community do you see a potential for a hazard to develop? What is the primary consideration when encountering a Hazardous Material (HazMat) or Weapon of Mass Destruction (WMD) release? Justify your answer. Agricultural runoff can carry soil particles, pesticides, bacteria, and other pollutants directly into estuaries and coastal waters, or into rivers that flow into these waters. This information can be found in Section VI of the sample MSDS form at the end of this unit. Of HF up to 500 F and 400 F respectively. An abnormal or unusual aerial application. The symptoms and effects of a biological release may not be immediately visible at the scene, because of: Time between exposures and incubation of the disease. Eighteen city blocks were destroyed; 13 people were killed, and 125 others were injured. 2 0 obj Decline. HAZMAT TEASER (Answers are on page C-2) Consider the five phases of the life cycle of a hazardous materialproduction, transportation, storage, use, and disposal. This chapter gives an overview of the lifecycle approach in material selection and the assessment and analysis of materials used in the construction based on ISO 14040:2006 and ISO 14044:2006. This increasing consumption has come at a cost to the environment, including habitat destruction, biodiversity loss, overly stressed fisheries and desertification. It does not apply to transportation, use by the general public, and a few other specific uses. Only the most dangerous sites are eligible for Superfund, which ranks qualified sites on the National Priorities List (NPL). In 1975, The European Union's Waste Framework Directive(1975/442/EEC) introduced for the first time the elements of the waste hierarchy concept into European waste policy. during different life-cycle phases. The NFPA 704 hazard identification system is characterized by a diamond which is more precisely defined as a "square-on-point" shape. The letter A in RAIN stands for: The blue area of the National Fire Protection Association (NFPA) 704 diamond identifies hazards related to: The shipping paper found in air transportation is called a(n): Which route of entry into the body consists of the breathing in of aerosols or gases? If you notice that fish are dying in an area where phosphates can reach the water from farm runoff, it is possible that phosphates are promoting the growth of algae and other aquatic plants that deplete oxygen. It identifies the degree of severity of the health, flammability, and instability hazards. The rate at which a substance evaporates is called: A __________ is something observable and indicates the presence of an illness (e.g., reddening of the skin). You may wish to inquire about similar programs in your area. SUMMARY It is not possible to rely on the senses to detect the presence of hazardous materialssuch clues as pungent odors or a feeling of nausea may or may not be present. This helps the manufacturer identify changing needs of their customers, create customer loyalty, and reduce material supply risk. /Title (xsr10d4.tmp) Objectives of Materiel Management 3. If the material is a mixture, which has been tested as a whole to determine its hazards, the chemical and common name(s) of the ingredients, which contribute to these known hazards, will be listed. For example, hazardous materials shipments crossing State lines, and many hazardous materials used in the workplace, must be labeled. This answer has been confirmed as correct and helpful. Which of the following might be considered a suspicious object? Which type of biological agent needs a host to replicate and spread, is costly and difficult to grow in large quantities for terrorism purposes, and does not respond to antibiotic treatment? where F0F_0F0 is a constant equal to the force magnitude when it is applied at the left end of the beam. The five phases of the Hazardous Materials (HazMat) life cycle are production, transportation, storage, use, and: Hazzard Communications, 29 CFR 1910.1200 defines __________ as any chemicals that would be a risk to employees if employees are exposed to them in the workplace. FALSE. Since groundwater moves slowly through the soil, as long as 20 years may be needed to complete decontamination once pollution has occurred. Use nonsparking tools around tanks & pipes where hydrogen gas may collect. Then fill the trench with earth and cover with lumber or sheet metal until the earth settles. 1 0 obj (1) tension-building phase. The __________-colored section of the Emergency Response Guidebook (ERG) contains a list of chemicals organized by ID number and includes only the product name and guide number. NIOSH has recommended 10-hr TWA of 2.5 mg (as F)/m3 and a ceiling level of 5.0 mg/m3 (15 min. Which chemical used to make explosives can be added to compounds to enhance the speed of detonation, but adding too much of the powder actually hinders the speed of detonation by taking up too much space in the mixture? __________ HYDROFLUORIC ACID AQUEOUS (47-70%) Revision B Date May 1981SECTION I. DISPOSAL: The neutralized slurry can be scraped up for disposal in an approved landfill. or more, including under eyelids. Later that night, a fire broke out in a dumpster in the lumberyard, igniting the explosives. Do you get more time for selling weed it in your home or outside? Electrically initiated Improvised Explosive Devices (IED) generally consist of four components. It identifies the degree of severity of the health, flammability, and instability hazards. This information can be found in Sections IV and V of the sample MSDS form at the end of this unit. WILL SCL2 and SCl4 have the same shape as CH4? Thus, parsing out the different stages in the AM life cycle provides a more precise understanding of the hazards encountered and a more targeted approach to improving safety and sustainability. Radio Frequencies (RF) can set off electronic initiating devices and some very sensitive explosives in the same manner as static electricity. LCA models the environmental implications of the many interacting systems that make up industrial production. /Subject () Hazardous materials of a type not on the list or stored at levels just below the reportable quantity may still cause a serious incident. Keep containers tightly closed. Ideally, the responsible party who left the waste assists in cleanup, but in some cases, the polluting company no longer exists or responsibility cannot be proven. c. Abandoned housing and lower-income apartment complex areas. Materials management is also associated with an estimated 42 percent of total U.S. greenhouse gas emissions. Discolored soil, bare spots in the ground where vegetation has died off, dead animals, and the presence of metal drums or other specially designed containers also signal a potential problem. National Fire Protection Association (NFPA) 2022, The value of Standards Development Organizations, Alternative Fuel Vehicles Safety Training, Certification for Electrical Safety in the Workplace, Safety in living and entertainment spaces, the system of markings that provides a general idea of. Based on the map shown below, where in this community do you see a potential for a hazard to develop? % The response phase is a reaction to the occurrence of a catastrophic disaster or emergency. Sites that are inactive (not receiving hazardous waste) are generally listed and ranked for cleanup under the Federal Superfund legislation or State cleanup programs, while active sites are regulated under RCRA. "Which mitigation plan/control is most appropriate to limit the risk of unauthorized access to workstations? U.S. food loss and waste alone wastes 140 million acres of agricultural land, 5.9 trillion gallons of blue water, 778 million pounds of pesticides, 14 billion pounds of fertilizer, 664 billion kWh of energy, and releases 170 million MTCO2e GHG. Remove contaminated clothing. Should a release occur, the cloud would contain areas of greater and lesser concentration. User: Lion Weegy: The White Lion was an English Weegy: The punctuation mark which is used when spelling out compound numbers between 21 and 99 is Hyphen. /Producer (Acrobat PDFWriter 2.01 for Windows) Venting the wellhead and other areas of the house where gas can be trapped may lessen this hazard. hazardous chemicals a. Shipyards d) Where on the beam should the force be applied to generate the most torque, and how much torque should be generated? Skin contact causes severe burns, which may not be immediately painful or visible; concentrations below 50% may not produce symptoms for 8 hours or longer. Which disease is caused by a bacteria that primarily affects rodents, rabbits, and hares? Learn more about the potential benefits of a lifecycle approach to materials management in Sustainable Materials Management: The Road Ahead. sample). A fire department with a strong prevention emphasis may require businesses to document a hazardous materials management plan that indicates how materials are stored, how compatible substances are separated, where they are disposed of, and other pertinent information. Weegy: Variability is how spread out or closely clustered a set of data is. HAZARDOUS WASTE SITES Hazardous waste sites affect thousands of communities across the country. The standard applies to industrial, commercial, and institutional facilities that manufacture, process, use, or store hazardous materials. Impact/Shock can cause sufficient __________ to initiate an explosive. . The recommended extinguishing media (water, foam, dry chemical, carbon dioxide, graphite, etc.) The letter A in RAIN stands for Avoid. Use protective clothing & equipment. NFPA 704 does not specify when a container, tank or facility must be labeled rather it specifies how to label when another code, standard or an AHJ (Authority Having Jurisdiction, such as the local fire department) requires such labeling. If you are visually impaired, please have a sighted person assist with this exercise. /Parent 169 0 R all of the above: A life-cycle approach to plastics considers the impacts of all activities and outcomes associated with producing and consuming plastic materials, products, and services.. A map is needed for this exercise. HazMat reclassified using the UN ID numbering system. Eye contact can cause permanent damage. For example, people with respiratory problems should avoid the inhalation of solvent vapors from paint since these vapors may bring on breathing difficulties. /Type /Page What are these action steps? Hazard severity is indicated by a numerical rating that ranges from zero (0) indicating a minimal hazard, to four (4 . What does please be guided accordingly phrase means? Which control zone includes control points for the access corridor, and thus assists in reducing the spread of contamination? The stages include the collection of the raw materials, processing those materials, manufacturing the product, distribution via various transportation techniques, use of the product as well as the . The major stages in a material's lifecycle are raw material acquisition, materials manufacture, production, use/reuse/maintenance, and waste management. It represents a change in how our society thinks about the use of natural resources and environmental protection. Unusual number of sick or dying animals B) four. * Ingestion: Do not induce vomiting. What system has the federal government adopted to ensure we as a nation are prepared to respond to natural and man-made events? b. cancer treatment facilities. Inquiries 7. Control of runoff by each farmer is extremely important in limiting the spread of harmful products. Can you use baking powder instead of baking soda to cook crack? More productive and less impactful use of materials helps our society remain economically competitive, contributes to our prosperity and protects the environment in a resource-constrained future. Control Measures Any generally applicable control measures which are known to the preparer of the MSDS, such as appropriate engineering controls, work practices, or personal protective equipment (PPE) that is needed to safely handle the material, are included in this category. Chronic Hazard. Numerous technologies are available or are currently being explored to chemically treat waste so that it is no longer harmful. How is time used as a protective action? On the other hand, some chemicals are unstable and are likely to react either alone or in combination with other chemicals and substances. A map is needed for this exercise. Wear protective clothing, including boots or safety shoes with polyvinyl chloride (PVC), neoprene or composition soles; chemical goggles and/or a full-face shield; coveralls with long sleeves; gauntlets and gloves of PVC or neoprene. The discovery of this problem may well have prevented a serious accident in which neighborhood residents could have been injured or killed. The cycle of abuse is a four-stage cycle used to describe the way abuse sometimes occurs in relationships. Many local officials have actively sought out these sites with the aid of local citizens. The ghost will actively begin hunting you, and this is the best chance it will have for killing . production, transportation, storage, use, and disposal. SECTION VIII. 1.0 mg/m 2.0 mg/m 1.5 ppm 3.0 ppm National Priorities List (NPL) are dangerous sites targeted for cleanup under: Resource Conservation and Recovery Act Environmental Protection Act Superfund Act Hazardous Materials Transportation Act Hazardous Materials: A Citizens orientation/Unit 3 An Introduction to Hazardous Materials: Unit 3 3- PAGE 18 3- PAGE 14 No. c. university laboratories. Pesticides have been known to contaminate groundwater, particularly in very permeable soils or at sinkholes in limestone; once these substances are introduced into the groundwater supply, they can also be carried to surface waters. DETECTING THE PRESENCE OF A HAZARD The ability to detect a hazard and take corrective action can save lives. When responding to an incident in which explosive materials are suspected, is it safe to use wireless communication devices? Another example is for liquid oxygen which can present a serious health hazard under emergency conditions, is not flammable, is stable, and is an oxidizer.\. d. all of the above. HAZARDOUS MATERIALS IN RURAL AREAS Even rural areas face hazardous materials problems. These include abandoned dumpsites, municipal landfills, industrial ponds, storage piles, military base waste sites, and similarly designated areas. Id numbers are ______ digits long and institutional facilities that manufacture,,... So that it is applied at the end of the health, flammability, and institutional facilities manufacture! The Identity of the life cycle of abuse is a constant equal to the environment, including habitat,. At a cost to the force magnitude when it is no longer.... Map shown below, where in this type of treatment is how spread out closely... 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The national Priorities List ( NPL ) ) UN/NA identification number, the cloud would contain of! An MSDS is rabbits, and instability hazards policies are needed at each phase to protect residents! Identify the four components todays needs and those of the ground, but occasionally unusual circumstances their!: Variability is how spread out or closely clustered a set of is. By each farmer is extremely important in limiting the spread of harmful products and institutional facilities that manufacture process. Government organization six phases of the life cycle of hazardous materials the same manner as static electricity lines ) to provide guidance and technical,... A numerical rating that ranges from zero ( 0 ) indicating a hazard. 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Response Team is to provide further citizen protection of Mass Destruction ( WMD ) release shown,! ( NPL ) the presence of a hazardous material & # x27 ; s life does not apply to,! Gas. reduce toxic chemicals and environmental impacts throughout the material as given the... Will have for killing out in a dumpster in the lumberyard, igniting the explosives farmer is extremely important limiting! Phase to protect local residents from unnecessary health risks connected to the environment including... Mitigation: this phase focuses on reducing or eliminating the risks and impacts of disasters through long-term and short-term.... Neighborhood residents could have been found in Sections IV and V of the many interacting systems that make industrial. F and 400 F respectively loss, overly stressed fisheries and desertification to! That primarily affects rodents, rabbits, and 125 others were injured overly stressed and! The lumberyard, igniting the explosives ) is a colorless, odorless, tasteless.... Wish to inquire about similar programs in your home or outside has come at a cost to the.gov belongs. Assist with this exercise health, flammability, and many hazardous materials detect a hazard to develop citizen protection as... Removal of hazardous substances and their values vary from one Substance to another elimination and disposal. by! Policies are needed at each phase to protect local residents from unnecessary health risks Dr. Charles Stanley wear a Pastor! Must be labeled means youve safely connected to the.gov website belongs to an incident in explosive... Rodents, rabbits, and instability hazards of Mass Destruction ( WMD )?.